ISSN: 2595-1939 https://doi.org/10.29396/jgsb.2023.v6.n3.2 Open access at jgsb.cprm.gov.br This work is licensed under a Creative Commons Attribution 4.0 Internacional License. Journal of the Geological Survey of Brazil vol 6, n3, 239-262, December 2023 Journal of the Geological Survey of Brazil Digital Supplement - Appendix 1 to 9 Lithogeochemistry and zircon U-Pb geochronology of the Granjeiro Complex and associated units, Curral Novo do Piauí, NW-Borborema Province, Brazil: implications for Archean to Paleoproterozoic crustal evolution José Alberto Rodrigues do Vale1* , Lena Virginia Soares Monteiro2 , Camila Franco Basto3 , Vladimir Cruz de Medeiros1 , Douglas Almeida Silveira3 , Evilarde Carvalho Uchôa Filho4 , Nilo Costa Pedrosa Junior5 , Joseneusa Brilhante Rodrigues6 , Ticiano José Saraiva dos Santos7 APPENDIX 1. Table with chemical analysis of major elements (wt. %) and traces (ppm) of the granodioritic to tonalitic orthogneisses of the Granjeiro Complex. Sample CB-03 DS-17B CB-R-18A CB-R-48 DS-12B CB-11 DS-10 DS-12A DS-20 DS-R-25 Major elements (wt. %) SiO2 70.59 68.56 70.3 66.6 65.74 63.51 63.7 71.16 69.35 68.8 TiO2 0.26 0.56 0.3 0.45 0.48 0.83 0.91 0.11 0.23 0.4 Al2O3 14.69 12.77 15.3 16.3 15.96 16.21 12.05 14.96 14.35 15.8 Fe2O3T 2.39 5.15 3.14 3.99 3.24 4.57 7.72 1.45 2.33 3.86 MgO 0.64 1.64 1.54 0.79 1.02 1.54 1.37 0.26 0.41 1.09 CaO 2.08 1.29 2.18 2.08 2.63 3.12 2.6 1.58 1.5 2.5 Na2O 4.75 4.3 3.51 4.15 4.32 4.19 3.33 4.14 3.93 4.82 K2O 2.54 2.44 4.3 4.47 3.93 2.45 2.85 4.4 4.2 2.34 P2O5 0.06 0.09 0.09 0.132 0.15 0.28 0.22 0.03 0.09 0.132 LOI 0.15 0.32 0.17 0.51 1.15 0.13 0.38 0.35 Total 98.150 97.120 100.660 98.962 97.640 97.210 95.900 98.220 96.770 99.742 Trace elements (ppm) Cr 4 <1 4 8.2 13 2 6 <1 <1 8 Ni 8.1 <0,5 5.9 11.6 8.2 1.6 7.3 1.8 1.1 8.2 Co 4.9 7.3 7.2 116.95 9.1 6.6 17.4 1.9 3.2 9 Ba 297 479 1306 1 1667 1061 1072 562 1548 455 Sr 134.5 42.6 297.4 4.3 556.5 548.1 143.2 229.1 308.9 289.4 Zr 131.1 353.1 141.3 42 95.1 88.2 246.8 65.9 176.6 41.1 Nb 18.2 38.3 7.7 2.98 16.3 41.5 21.1 8.3 19 7.7 Y 23 82.2 9.97 11.14 7.02 43.8 76.9 5.6 17.24 6.82 V 13 32 16 1.5 33 43 30 11 14 20 La 19.3 122.3 135.3 3.23 38.1 105.3 72.4 10.7 91.6 24.1 Ce 31.63 194.26 221.58 <0.02 70.67 156.21 108.48 19.34 142.17 45.46 Pr 6.29 21.7 21.87 15.11 9.3 20.72 11.13 3.06 16.56 8.06 Nd 21.2 80.5 68 49.9 31.8 75.1 43.2 10.8 52.7 29.1 Sm 4.1 15.9 8.2 6.8 4.5 13.4 9 1.7 7.8 4.2 Eu 0.82 2.07 1.26 1.29 1.15 2.46 1.82 0.44 1.2 0.9 Gd 3.91 16.23 4.58 4.24 2.99 11.84 10.42 1.32 5.74 2.75 Tb 0.68 2.61 0.53 0.51 0.34 1.7 1.63 0.18 0.75 0.31 Dy 4.23 17.04 2.35 2.51 1.58 9.55 10.21 0.93 3.62 1.43 Ho 0.86 3.47 0.37 0.44 0.26 1.77 2.08 0.18 0.68 0.26 Er 2.5 10.34 0.96 1.07 0.69 4.86 6.08 0.56 1.83 0.65 Tm 0.36 1.48 0.13 0.15 0.11 0.62 0.87 0.09 0.25 0.1 Yb 2.2 9.8 0.7 0.9 0.6 3.8 5.4 0.6 1.6 0.5 Lu 0.31 1.39 0.09 0.11 0.08 0.52 0.78 0.11 0.23 0.09 Cs 2.33 1.07 2.02 1.7 3.75 1.26 0.72 3.33 1.15 1.71 Rb 83.7 85.7 150.2 118.8 134.8 63.5 87 158.8 97.8 70.2 Th 7 25.9 58.5 40.7 9.3 14.2 12 14.2 38 11.4 U 2 3.51 3.36 2.38 1.79 1.16 2.95 3.22 2 0.61 Ta 0.57 2.14 0.58 0.79 0.46 1.98 1.24 1.21 0.68 0.23 Pb 15.6 5.8 32.3 406 30.5 17.3 13.5 41.7 17.8 10.2 https://doi.org/10.29396/jgsb.2023.v6.n3.2 https://jgsb.cprm.gov.br/index.php/journal https://creativecommons.org/licenses/by/4.0/ https://creativecommons.org/licenses/by/4.0/ https://orcid.org/0009-0003-8865-7348 https://orcid.org/0000-0001-6486-1510 https://orcid.org/0000-0003-4381-0962 https://orcid.org/0000-0001-5329-8187 https://orcid.org/0000-0002-9491-1213 https://orcid.org/0000-0003-1638-2050 https://orcid.org/0009-0008-6051-8553 https://orcid.org/0000-0003-3999-026X https://orcid.org/0000-0001-9397-491X https://doi.org/10.29396/jgsb.2023.v6.n3.2 Vale et al. - JGSB 2023, vol 6 n3 APPENDIX 2. Table with chemical analysis of major elements (wt. %) and traces (ppm) of the syenogranitic to syenitic orthogneisses of the Granjeiro Complex. Sample JR-R-298 JR-R-333 JR-R-299 JR-R-300 Major elements (wt. %) SiO2 73.3 73.2 74.4 74.1 TiO2 0.35 0.35 0.38 0.36 Al2O3 12.5 12 12.2 12.3 Fe2O3T 4.13 4.29 4.45 4.58 MgO 0.17 0.12 <0.1 0.13 CaO 1.36 1 1.54 1.07 Na2O 3.32 2.53 3.57 3.03 K2O 4.87 5.67 3.7 4.43 P2O5 0.052 0.046 0.045 0.048 LOI 0.04 0.29 0.18 0.35 Total 100.092 99.496 100.465 100.398 Trace elements (ppm) Cr 3 2 <1 <1 Ni 3 2 <1 <1 Co 3 2.5 2.3 1.9 Ba 1191 1151 1322 1358 Sr 88 48.4 98.8 60.4 Zr 561.9 628.9 547.3 646.4 Nb 37.5 41.64 36.26 35.02 Y 66.79 91.96 105.17 71.69 V 5 3 1 2 La 26.5 42.4 105.9 19.1 Ce 173.7 168.7 224.3 141.6 Pr 7 11.16 27.36 4.7 Nd 28 43.1 100.1 19 Sm 8.1 10.6 21 5.8 Eu 1.48 1.6 3.54 1.3 Gd 9.87 12.14 20.02 8.4 Tb 1.87 2.39 3.46 1.75 Dy 12.9 16.48 22.18 12.99 Ho 2.72 3.62 4.49 2.81 Er 8.22 11.21 13.53 8.79 Tm 1.24 1.68 2.02 1.38 Yb 8.3 11 13.4 8.8 Lu 1.16 1.56 1.82 1.16 Cs 0.17 0.58 0.08 0.28 Rb 134 162 60.4 96.6 Th 19.5 16.4 21.9 19.2 U 3.07 1.74 2.33 1.4 Ta 2.63 2.04 2.45 2.63 Pb 19.6 10.4 9.6 13.2 Crustal evolution of the Granjeiro Complex, Borborema Province APPENDIX 3. Table with chemical analysis of major elements (wt. %) and traces (ppm) of the metamafic rocks of the Granjeiro Complex. Sample DS-07 CB-05 CB-10 DS-R-06C JR-R-311 JR-R-323A JR-R-321 JR-R-303 JR-R-329A JR-R-316A JR-R-342i JR-R-340A JR-R-340G JR-R-341E JR-R-342F JR-R-344 JR-R-346 Major elements (wt. %) SiO2 51.38 50.4 54.6 52.4 51 50.1 50.3 55.1 49.3 50.4 42.1 47.3 51 45.7 46.1 52.5 49.7 TiO2 0.73 1.17 1.02 0.67 1.15 1.41 1.35 0.74 1.08 1.4 1.53 1.04 2.11 1.27 0.96 0.9 1.66 Al2O3 12.48 13.88 14.9 11 13.6 14.2 14.7 10.5 13.7 14.1 17.3 16.3 12.7 12.8 13.5 13.1 13.2 Fe2O3T 10.47 14.68 10.68 11.9 14.9 12.2 14.5 11.7 14.2 14.2 16.2 13.9 18 23.9 13.4 13.6 16.8 MgO 8.86 6.76 6.55 10.5 6.43 7.1 6.52 9.19 7.57 6.73 8.88 7.69 4.64 5.99 7.42 7.67 5.47 CaO 10.88 9.34 9.03 10.7 9.59 10.6 10.5 9.38 10.2 10 7.77 8.92 8.66 5.7 6.99 8.65 8.36 Na2O 2.09 2.62 2.91 1.69 2.38 3.11 1.94 2.04 2.92 2.23 2.71 3.03 2.45 0.72 1.64 2.81 2.56 K2O 0.42 0.27 0.34 0.33 0.4 0.78 0.21 0.83 0.63 0.27 2.61 0.8 0.44 3.94 6.61 0.73 1.26 P2O5 0.07 0.09 0.12 0.076 0.114 0.177 0.122 0.092 0.096 0.124 0.113 0.132 0.235 0.121 0.081 0.09 0.157 LOI 0.73 0.4 0.46 0.99 0.55 0.55 0.71 0.82 0.49 0.87 1.11 0.84 0.75 0.77 3.24 0.67 1.23 Total 98.110 99.610 100.610 100.256 100.114 100.227 100.852 100.392 100.186 100.324 100.323 99.952 100.985 100.911 99.941 100.720 100.397 Trace elements (ppm) Cr 153 28 71 65.5 29 97 62 249 20 95 55 40 10 87 87 36 9 Ni 205.7 55 86.4 2.6 50 161 89 218 77 109 129 196 52 90 101 82 60 Co 65.1 64.1 54 9.47 44.4 46.7 47.2 56.8 55.1 50.5 80 69.3 54.7 63.3 52.2 52.6 61 Ba 121 175 51 2 86 122 30 47 84 47 740 119 36 504 1012 104 215 Sr 148.8 137.3 249.3 0.9 129.9 213.5 144.2 92 140.6 194.1 273.6 173.7 138.7 19.1 286.6 112.3 166.7 Zr 19.8 19 49.5 67 58.4 38.6 68.4 49.9 92.6 74.1 92.3 101.3 171.1 119.7 58 56.8 112.9 Nb 8.1 5.8 10.3 1.43 2.77 2.96 3.11 2.78 3.62 3.76 5.2 5.7 9.5 7.06 3.71 3.61 6.46 Y 20.3 28.3 26.3 0.4 21.13 21.84 21.98 14.07 19.37 22.33 21.79 22.26 38.85 27.41 13.5 18.01 29.04 V 232 289 220 0.1 213 268 279 196 258 281 204 99 172 200 126 156 196 La 8.3 8.4 20.6 0.28 4.1 7.3 6.3 6.3 9.7 19.2 9.7 10.6 16.7 24.8 5.2 5.6 9 Ce 14.08 15.38 38.64 0.08 9.3 12.3 11.6 8.4 13.9 11.7 16.2 20.8 31.9 30.1 10.1 10.9 20.5 Pr 1.44 2.04 3.84 0.82 1.6 1.92 1.83 1.27 2.45 1.87 2.32 2.83 4.56 3.87 1.55 1.59 3.12 Nd 6.5 10.1 16 3.9 7.8 9.3 8.7 5.5 11 9.3 11.2 12 20.7 16.6 7.4 7.4 15.2 Sm 1.9 3.1 3.7 1.3 2.5 2.7 2.7 1.7 2.9 3 3.4 3.1 5.4 4 2.2 2.2 4.5 Eu 0.74 1.12 1.11 0.5 0.89 1.22 0.94 0.64 1.01 1.06 1.63 1.07 1.84 1.05 0.8 0.8 1.52 Gd 2.58 3.81 4.05 1.78 3.28 3.43 3.46 2.36 3.64 3.79 3.85 3.91 6.78 4.92 2.77 3.15 5.32 Tb 0.44 0.68 0.66 0.34 0.55 0.62 0.57 0.39 0.6 0.62 0.66 0.64 1.17 0.87 0.41 0.52 0.89 Dy 3.03 4.29 4 2.37 3.6 4 3.84 2.65 3.63 4.21 4.17 4.1 7.44 5.32 2.66 3.46 5.7 Ho 0.62 0.89 0.8 0.51 0.77 0.85 0.8 0.57 0.73 0.91 0.85 0.88 1.51 1.06 0.55 0.71 1.15 Er 1.84 2.63 2.34 1.49 2.4 2.46 2.36 1.6 2.18 2.51 2.56 2.63 4.32 2.93 1.43 2.02 3.35 Tm 0.26 0.38 0.33 0.23 0.33 0.35 0.34 0.22 0.31 0.38 0.34 0.38 0.64 0.39 0.23 0.33 0.5 Yb 1.7 2.4 2.2 1.4 2.2 2.4 2.3 1.5 2 2.5 2.2 2.4 4.4 2.5 1.3 2 3.2 Lu 0.24 0.36 0.31 0.21 0.31 0.37 0.35 0.13 0.24 0.3 0.25 0.3 0.56 0.3 0.11 0.24 0.42 Cs 0.74 <0,05 0.4 0.24 0.11 0.14 0.26 0.34 0.14 0.51 18.57 0.73 0.12 11.14 21.23 0.71 1.79 Rb 11.4 3.8 7.9 4.7 6.7 8.1 4.3 22.4 12.3 2.1 176.9 18.1 4.4 194.6 611.5 27.3 51.9 Th 4.8 0.2 13 0.7 <0.1 <0.1 <0.1 1.4 1.3 0.7 3.1 2.6 3.1 2.6 0.9 1.1 0.8 U 0.33 0.14 0.56 0.07 0.06 0.29 0.16 0.76 0.31 0.14 0.38 0.59 0.35 0.9 0.24 0.2 0.16 Ta 0.6 <0,05 1.47 0.17 <0.05 <0.05 <0.05 0.69 0.33 0.21 0.18 0.29 0.8 0.45 0.09 0.11 0.27 Pb 2.8 5.3 8.6 279 9.8 11.8 3 6.3 17.3 5.3 29.3 14.4 9.5 7.4 28.8 28.2 15 Vale et al. - JGSB 2023, vol 6 n3 APPENDIX 4. Table with chemical analysis of major elements (wt. %) and traces (ppm) of the metaultramafic rocks of the Granjeiro Complex. Sample DS-R-23A JR-R-332 JR-R-315 JR-R-327 JR-R-309 CB-R-07A Elementos maiores (%) SiO2 49.7 50.9 48.9 44.7 44.4 51.4 TiO2 0.23 0.3 0.43 1.13 1.72 0.47 Al2O3 10.1 4.92 6.14 6.86 7.47 4.55 Fe2O3T 7.52 9.31 12.8 15.1 15.3 11.4 MgO 11.5 19.6 20.1 20.5 18.1 20.3 CaO 18 12.2 8.54 8.5 8.48 9.54 Na2O 0.85 0.91 0.24 0.46 0.32 0.23 K2O 0.28 0.25 0.02 0.08 0.04 0.02 P2O5 0.073 0.038 0.06 0.125 0.159 0.06 LOI 1.12 1.58 3.19 3.62 3.82 3.05 Total 99.373 100.008 100.420 101.075 99.809 101.020 Elementos traços (ppm) Cr 343 721 625 612 455 609 Ni 237.7 392 567 939 665 526 Co 65 66.9 80.5 94.5 48.9 77.3 Ba 35 63 10 15 14 12 Sr 80.8 88.7 6 39.3 18.2 11.5 Zr 10.4 24.9 60.1 73 166.1 79.1 Nb 2 1.59 4.19 4.9 14.5 4.71 Y 14.7 11.31 23.55 16.52 19.22 14.17 V 112 119 109 201 169 100 La 8.3 6.4 17.4 9.5 15.1 7.1 Ce 15.73 11.6 19.2 17.4 31.2 9.2 Pr 1.98 1.76 3.78 2.8 4.85 1.66 Nd 7.9 7.4 15.4 13 20.9 7.6 Sm 1.5 1.8 3.4 3.3 5 2 Eu 0.43 0.5 0.67 0.92 1.36 0.6 Gd 1.67 1.89 3.83 3.53 5.17 2.76 Tb 0.28 0.32 0.57 0.56 0.81 0.43 Dy 1.98 1.98 3.49 3.46 4.5 2.58 Ho 0.43 0.42 0.71 0.63 0.8 0.55 Er 1.36 1.2 2.03 1.86 2.32 1.54 Tm 0.22 0.19 0.28 0.24 0.29 0.2 Yb 1.4 1.2 1.8 1.6 1.7 1.3 Lu 0.21 0.18 0.27 0.26 0.17 0.15 Cs 0.48 <0.05 0.05 0.06 0.05 0.05 Rb 2.2 2.4 0.3 0.7 0.3 0.5 Th 1 0.2 0.8 0.3 3.5 2.4 U 0.16 0.26 0.39 0.24 0.45 0.55 Ta 0.08 <0.05 <0.05 <0.05 1.01 0.42 Pb 3.3 6.7 3 3.1 3.2 2.1 Crustal evolution of the Granjeiro Complex, Borborema Province APPENDIX 5. Table with chemical analysis of major elements (wt. %) and traces (ppm) of the banded iron rocks of the Granjeiro Complex. Sample JR-R-334 JR-R-312 JR-R-305 JR-R-311B JR-R-316B JR-R-314 JR-R-287 JR-R-313 JR-R-318 JR-R-340B JR-R-340D JR-R-340F JR-R-341B JR-R-341D JR-R-341F JR-R-342E Major elements (wt. %) SiO2 41.8 50.6 41.1 34.9 42.4 42.1 44.1 29.2 45.1 40 37.9 40 48.5 40.2 43.7 45.4 TiO2 0.02 0.02 0.02 0.02 0.02 0.01 0.03 0.02 0.02 0.03 0.02 0.03 0.28 0.04 0.05 0.09 Al2O3 0.46 0.61 0.48 0.65 0.56 0.39 0.59 0.69 0.51 0.4 0.23 0.54 4.38 0.42 0.72 1.04 Fe2O3T 56.6 49.6 56.2 63.1 55.9 55.1 53.2 67.1 53.6 56.5 60.1 57.6 41 58.3 51.2 50.1 MgO 0.88 0.31 0.96 0.67 0.27 0.91 1.13 1.69 0.54 1.66 1.53 1.64 2.39 1.66 1.61 1.96 CaO 0.36 0.12 0.9 0.49 0.17 0.57 0.66 0.39 0.05 2.23 1.4 1.21 1.76 0.87 1.5 1.46 Na2O 0.26 <0.1 0.1 0.13 <0.1 0.11 0.11 0.71 <0.1 0.14 0.12 0.21 0.26 0.22 0.13 0.11 K2O 0.32 0.31 0.02 0.3 0.12 0.22 0.39 0.47 0.23 0.03 0.12 0.2 1.46 0.28 0.21 0.29 P2O5 0.049 0.132 0.062 0.072 0.051 0.051 0.033 0.049 0.088 0.098 0.069 0.076 0.125 0.059 0.111 0.118 LOI 0.29 -0.63 0.63 0.36 0.51 0.35 0.39 0.41 0.61 -0.95 -1.29 -1.4 -0.3 -1.46 -1.42 -1.18 Total 101.039 101.072 100.472 100.692 100.001 99.811 100.633 100.729 100.748 100.138 100.199 100.106 99.855 100.589 97.811 99.388 Trace elements (ppm) Cr <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 23 <1 <1 <1 Ni <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 11.4 <0.5 <0.5 <0.5 Co 1.7 6.7 1.1 1.4 2.1 1.4 1.3 1.2 1.4 1.9 0.9 1.2 10.8 1.3 2.1 4.4 Ba 71 70 <5 573 136 447 265 64 485 <5 32 <5 230 19 14 23 Sr 4.1 9.4 10.4 17.2 6.1 21 9.6 6.1 19.1 30.1 20.3 16.4 9.3 7 21.2 10.9 Zr 8 8.8 8 8.8 8.5 8.2 7.6 7.9 8.5 9.9 8.9 9.2 51.9 9.4 15.4 10.5 Nb 0.6 0.8 0.7 0.5 0.5 0.8 0.5 0.4 0.6 0.4 0.5 0.6 4.8 0.4 0.7 1.4 Y 3.32 8.53 10 5.29 20.28 37.72 4.91 10.59 9.32 3.56 3.97 5.23 15.32 4.19 5.07 5.54 V 11 23 17 10 13 12 11 11 12 13 12 13 40 14 14 22 La 3.6 1.5 3.4 1.9 26.2 16.6 3.8 4.4 8.3 1.3 1.1 1.7 9.4 1.4 1.8 2.6 Ce 9.1 2.79 3.54 2.77 30.63 13.81 4.33 3.61 8.01 2.33 1.85 3.06 18.09 2.37 3.5 5.17 Pr 1.01 0.43 0.85 0.63 6.72 3.87 1.18 0.89 1.45 0.48 0.45 0.67 2.82 0.62 0.59 0.8 Nd 4.1 1.8 3.5 2.6 23.4 15.5 4.7 3.5 5.7 1.9 1.6 2.4 10.7 2.2 2.2 3.2 Sm 0.7 0.4 0.7 0.5 4.6 3.2 1 0.6 1 0.3 0.2 0.4 2.2 0.4 0.6 0.7 Eu 0.15 0.14 0.2 0.15 1.13 0.99 0.2 0.2 0.31 0.08 0.05 0.1 0.62 0.08 0.14 0.16 Gd 0.54 0.79 0.96 0.62 3.61 3.99 0.87 0.92 1.28 0.37 0.38 0.51 2.37 0.54 0.6 0.65 Tb 0.08 0.15 0.16 0.1 0.62 0.61 0.13 0.15 0.18 0.06 0.07 0.09 0.35 0.08 0.1 0.13 Dy 0.42 1.06 1.08 0.64 3.53 3.89 0.75 0.88 1.04 0.35 0.38 0.56 2.17 0.42 0.63 0.73 Ho 0.09 0.25 0.24 0.13 0.65 0.86 0.14 0.23 0.24 0.08 0.09 0.12 0.46 0.09 0.15 0.16 Er 0.28 0.71 0.66 0.45 1.87 2.52 0.41 0.71 0.65 0.25 0.29 0.38 1.33 0.32 0.43 0.51 Tm <0.05 0.1 0.14 0.07 0.28 0.36 0.07 0.09 0.08 <0.05 <0.05 0.06 0.21 <0.05 0.06 0.09 Yb 0.2 0.6 0.7 0.4 1.6 2 0.4 0.6 0.6 0.2 0.2 0.3 1.2 0.2 0.4 0.5 Lu <0.05 0.07 0.14 0.06 0.2 0.3 0.05 0.09 0.08 <0.05 <0.05 <0.05 0.11 <0.05 <0.05 <0.05 Cs 0.07 0.69 0.06 0.09 0.25 0.26 0.5 0.06 1.89 0.13 <0.05 0.43 4.5 0.25 1.28 1.3 Rb 4.6 19.7 0.6 5.5 3.1 8.6 13.1 15.4 37.1 1.5 3.4 12.8 80.2 12.2 13.8 18.7 Th 1.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.8 0.7 0.7 3.5 1 0.9 2.4 U 0.13 0.13 0.4 0.14 0.14 0.1 0.14 0.14 0.06 0.11 0.39 0.21 0.99 0.21 0.24 0.21 Ta <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.47 0.07 <0.05 <0.05 Pb 2.4 2.8 1.4 3.1 9.5 5.7 4.1 2.3 21.7 2.6 3 2.7 8.6 1.8 28.7 1.3 Vale et al. - JGSB 2023, vol 6, n3 CB-03 Ratios Ages Spot f(206) 204Pb 206Pb Th/U 206Pb/204Pb 1σ 207Pb/206Pb 1σ 207Pb/235U 1s 206Pb/238U 1σ Rho 207Pb/206Pb 2σ 206Pb/238U 2σ 207Pb/235U 2σ U-Pb disc 12 0.01 14 0.0050 0.24 188518 21.04 0.27490 1.27 27.079 1.49 0.71439 0.69 0.46 3334 39 3475 37 3386 29 -4.22 13 0.05 49 0.0121 0.18 30610 26.63 0.27805 1.21 25.185 2.36 0.65689 1.99 0.84 3352 38 3255 101 3315 46 2.89 18 0.02 26 0.0038 0.20 65692 24.26 0.27387 0.96 26.889 1.19 0.71202 0.60 0.51 3328 30 3466 32 3379 23 -4.14 22 0.01 12 0.0039 0.59 170006 23.75 0.27730 0.77 27.468 1.02 0.71836 0.57 0.55 3348 24 3490 31 3400 20 -4.24 23 0.00 22 0.0121 0.18 291283 29.28 0.27532 0.72 26.813 1.07 0.70626 0.69 0.65 3337 22 3444 37 3377 21 -3.23 24 0.01 11 0.0070 0.26 238237 19.07 0.27911 0.90 27.245 1.10 0.70791 0.53 0.48 3358 28 3451 28 3392 22 -2.76 25 0.03 13 0.0015 0.43 39897 22.63 0.28121 1.67 25.837 2.27 0.66633 1.50 0.66 3370 52 3292 77 3340 44 2.31 26 0.03 40 0.0028 0.41 43103 52.78 0.27374 1.32 25.578 1.70 0.67763 1.01 0.59 3328 41 3335 52 3331 33 -0.23 34 0.01 248 0.0126 0.32 99967 54.70 0.27962 1.18 26.537 1.46 0.68825 0.77 0.53 3361 37 3376 40 3367 28 -0.45 3 1.30 0.09 1023 0.28091 1.44 21.306 3.81 0.55008 3.48 0.92 3368 22 2826 80 3153 36 83.89 5 0.28 300 0.0185 0.08 5466 17.68 0.12462 1.27 6.454 1.42 0.37563 0.53 0.37 2023 45 2056 19 2040 25 -1.60 6 0.00 17 0.0278 0.25 694547 25.57 0.11949 0.60 6.189 0.86 0.37563 0.49 0.57 1949 21 2056 17 2003 15 -5.50 7 0.00 21 0.0305 0.20 842212 23.73 0.11905 0.60 6.287 0.87 0.38296 0.50 0.58 1942 22 2090 18 2017 15 -7.63 9 0.58 993 0.0253 0.06 2618 19.35 0.12422 1.33 6.515 1.49 0.38036 0.57 0.38 2018 47 2078 20 2048 26 -2.99 11 0.02 578 0.0292 0.24 78435 61.83 0.12759 1.47 6.860 1.64 0.38993 0.60 0.37 2065 52 2123 22 2094 29 -2.78 17 0.00 105 0.0326 0.26 321985 54.90 0.11779 0.70 6.501 1.00 0.40029 0.62 0.62 1923 25 2170 23 2046 18 -12.87 32 0.12 228 0.0214 0.00 12728 17.60 0.12788 1.19 7.202 1.43 0.40844 0.70 0.49 2069 42 2208 26 2137 25 -6.71 33 0.04 150 0.0107 0.00 43284 47.38 0.11803 1.38 5.403 1.55 0.33196 0.61 0.39 1927 49 1848 19 1885 26 4.09 14B 0.02 80 0.0186 0.00 92771 51.50 0.13757 1.24 7.831 1.44 0.41281 0.63 0.44 2197 43 2228 24 2212 26 -1.41 APPENDIX 6. Summary of LA-ICP-MS data of zircons from the migmatitic orthogneiss sample (CB-03). Crustal evolution of the Granjeiro Complex, Borborema Province JR-333 Ratios Ages Spot f206 U Th Pb Th/U 206Pb/204Pb 238U/206Pb 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ Rho 208Pb/232Th 1σ 207Pb/206Pb 2σ 206Pb/238U 2s 207Pb/235U 2σ 208Pb/232Th 2σ % conc 100 0.00 229 145 213 0.63 65800000 1964637.0000 0.0579 0.1767 0.0030 12.390 0.310 0.5090 0.0150 1.18 0.1538 0.0045 2639 15 2644 64 2638 24 3000 130 100 101 0.20 35 16 21 0.45 9365 2024291.0000 0.0615 0.1723 0.0048 11.850 0.310 0.4940 0.0150 1.16 0.1541 0.0084 2617 29 2580 65 2588 25 2600 1100 99 104 0.15 50 25 36 0.50 12600 1964637.0000 0.0540 0.1756 0.0043 12.010 0.310 0.5090 0.0140 1.07 0.1751 0.0083 2658 25 2650 59 2608 25 3460 680 100 105 0.08 96 44 63 0.46 23150 2016129.0000 0.0569 0.1784 0.0038 11.810 0.280 0.4960 0.0140 1.19 0.1710 0.0058 2668 19 2575 59 2579 22 3050 350 97 110 0.04 178 86 134 0.49 43850 2012072.0000 0.0607 0.1774 0.0042 12.560 0.320 0.4970 0.0150 1.18 0.1603 0.0056 2671 25 2585 64 2634 24 3000 210 97 114 0.00 329 174 246 0.53 82200000 1945525.0000 0.0492 0.1784 0.0035 12.690 0.300 0.5140 0.0130 1.07 0.1470 0.0042 2650 18 2654 56 2654 23 2830 100 100 115 0.00 193 95 133 0.49 50550000 1941748.0000 0.0452 0.1788 0.0030 12.820 0.260 0.5150 0.0120 1.15 0.1416 0.0043 2666 16 2665 52 2665 19 2780 150 100 APPENDIX 7. Summary of LA-ICP-MS data of zircons from the syenogranitic orthogneiss sample (JR-333). Vale et al. - JGSB 2023, vol 6, n3 DS-07 Ratios Ages Spot Pb Th U Th/U 207Pb/235U 1σ 206Pb/238U 1σ Rho 238U/206Pb Rho 207Pb/206Pb 1σ 207Pb/206Pb 1σ 206Pb/238U 1σ 207Pb/235U 1σ 207Pb/206Pb 1σ 16.2 52 26 105 0.25 7.5152 0.1970 0.4008 0.0040 0.75 2.4953 0.0246 0.1360 0.0037 0.0800 0.0041 2.173 0.018 2.175 0.024 2.177 0.048 3.2 46 21 91 0.24 7.5080 0.1724 0.3987 0.0044 0.04 2.5084 0.0277 0.1366 0.0034 0.0784 0.0049 2.163 0.020 2.174 0.020 2.184 0.042 18.1 43 30 82 0.36 7.7951 0.2080 0.4100 0.0041 0.46 2.4393 0.0245 0.1379 0.0038 0.1420 0.0097 2.215 0.019 2.208 0.024 2.201 0.049 2.1 66 44 122 0.36 7.8766 0.1630 0.4126 0.0043 0.87 2.4235 0.0250 0.1384 0.0031 0.1293 0.0047 2.227 0.020 2.217 0.019 2.208 0.039 6.1 50 25 97 0.26 7.7593 0.1718 0.4073 0.0044 0.37 2.4555 0.0266 0.1382 0.0033 0.0902 0.0043 2.202 0.020 2.203 0.020 2.205 0.041 4.1 28 13 52 0.26 7.6674 0.2014 0.4057 0.0051 0.35 2.4646 0.0308 0.1371 0.0040 0.0892 0.0054 2.195 0.023 2.193 0.024 2.190 0.050 7.1 47 36 89 0.41 7.8429 0.1807 0.4122 0.0046 0.32 2.4258 0.0273 0.1380 0.0035 0.1340 0.0069 2.225 0.021 2.213 0.021 2.202 0.044 14.1 25 13 47 0.28 7.8384 0.2745 0.4045 0.0051 0.28 2.4724 0.0310 0.1406 0.0053 0.1015 0.0070 2.190 0.023 2.213 0.032 2.234 0.066 8.1 17 7 33 0.20 7.9782 0.2626 0.4203 0.0064 0.11 2.3791 0.0359 0.1377 0.0052 0.0739 0.0083 2.262 0.029 2.229 0.030 2.198 0.065 17.1 30 14 61 0.23 7.7442 0.2203 0.4076 0.0043 0.82 2.4536 0.0258 0.1378 0.0041 0.0760 0.0040 2.204 0.020 2.202 0.026 2.200 0.053 11.1 52 32 103 0.31 7.8213 0.2082 0.4107 0.0041 0.79 2.4347 0.0245 0.1381 0.0038 0.1045 0.0049 2.218 0.019 2.211 0.024 2.204 0.048 7.2 43 23 83 0.27 7.6963 0.1744 0.4073 0.0045 0.45 2.4553 0.0270 0.1371 0.0034 0.0904 0.0037 2.203 0.021 2.196 0.020 2.190 0.043 15.1 82 63 158 0.40 7.7279 0.1980 0.4083 0.0040 0.01 2.4493 0.0237 0.1373 0.0036 0.1132 0.0139 2.207 0.018 2.200 0.023 2.193 0.046 9.1 51 30 98 0.30 7.8867 0.2129 0.4160 0.0043 0.55 2.4037 0.0246 0.1375 0.0038 0.1136 0.0056 2.242 0.019 2.218 0.024 2.196 0.049 1.1 19 13 35 0.37 7.8917 0.2551 0.4134 0.0062 0.54 2.4189 0.0366 0.1384 0.0050 0.1378 0.0116 2.230 0.028 2.219 0.029 2.208 0.062 5.2 52 32 103 0.32 7.6247 0.1687 0.4016 0.0043 0.55 2.4898 0.0267 0.1377 0.0033 0.1043 0.0025 2.177 0.020 2.188 0.020 2.198 0.041 10.1 44 23 85 0.27 7.8511 0.2150 0.4088 0.0042 0.08 2.4462 0.0251 0.1393 0.0040 0.0892 0.0053 2.209 0.019 2.214 0.025 2.218 0.049 12.1 23 14 46 0.30 7.6424 0.2604 0.3944 0.0049 0.29 2.5354 0.0314 0.1405 0.0051 0.0975 0.0086 2.143 0.023 2.190 0.031 2.234 0.064 13.1 29 10 59 0.18 7.5388 0.2156 0.3980 0.0042 0.37 2.5128 0.0264 0.1374 0.0041 0.0634 0.0050 2.160 0.019 2.178 0.025 2.195 0.051 5.1 8 4 16 0.25 7.9771 0.3944 0.4013 0.0090 0.01 2.4921 0.0559 0.1442 0.0084 0.0765 0.0151 2.175 0.041 2.228 0.045 2.278 0.102 APPENDIX 8. Summary of LA-ICP-MS data of zircons from the amphibolite sample (DS-07). Crustal evolution of the Granjeiro Complex, Borborema Province APPENDIX 9. Summary of LA-ICP-MS data of zircons from the pegmatite intrusive body sample (JR-289A). JR-289A Ratios Ages Spot 206Pb/204Pb f(206) U Th/U Pb208/Th232 2σ 207Pb/206Pb 2σ 207Pb/235U 2σ 206Pb/238U 2σ Rho 207Pb/206Pb 2σ 206Pb/238U 2s 207Pb/235U 2σ 208Pb/232Th 2σ Rho 156 0 0.00 54.42 0.80 0.09085 2.60 0.10608 1.19 4.633 2.00 0.31675 1.61 0.80 1733 22 1774 25 1755 17 1758 44 102.35 127 351 0.85 84.80 1.40 0.08738 1.81 0.10814 1.92 4.717 2.50 0.31638 1.60 0.64 1768 35 1772 25 1770 21 1693 30 100.21 140 0 0.00 196.71 0.43 0.10055 1.73 0.13074 1.02 6.959 1.73 0.38604 1.40 0.81 2108 18 2104 25 2106 16 1937 32 99.83 128 0 0.00 66.52 0.42 0.10895 3.34 0.13057 1.15 6.961 1.98 0.38667 1.61 0.81 2106 20 2107 29 2106 18 2090 66 100.08 139 0 0.00 174.80 1.30 0.10025 1.76 0.13323 1.07 7.375 1.79 0.40145 1.43 0.80 2141 19 2176 27 2158 16 1931 32 101.62 143 0 0.00 79.14 1.08 0.10491 1.87 0.13311 1.07 7.412 1.83 0.40384 1.49 0.81 2139 19 2187 28 2162 17 2017 36 102.21 130 0 0.00 135.36 0.76 0.09789 2.27 0.13478 1.09 7.414 1.89 0.39893 1.54 0.82 2161 19 2164 28 2163 17 1888 41 100.14 145 687 0.45 65.62 0.77 0.10140 2.86 0.13578 1.36 7.439 2.16 0.39736 1.69 0.78 2174 24 2157 31 2166 20 1952 53 99.21 157 0 0.00 110.43 0.72 0.11270 2.09 0.13489 1.09 7.441 1.85 0.40011 1.50 0.81 2163 19 2170 28 2166 17 2158 43 100.32 162 0 0.00 81.82 0.73 0.10790 2.67 0.13613 1.15 7.527 1.98 0.40101 1.61 0.81 2179 20 2174 30 2176 18 2071 52 99.78 126 0 0.00 125.39 0.96 0.12727 1.95 0.17959 1.06 12.596 1.84 0.50867 1.51 0.82 2649 18 2651 33 2650 17 2421 44 100.07 133 0 0.00 106.58 1.48 0.12487 1.91 0.17899 1.07 12.627 1.87 0.51164 1.54 0.82 2644 18 2664 34 2652 18 2378 43 100.76 141 0 0.00 57.11 0.94 0.12496 2.46 0.17924 1.11 12.635 1.97 0.51127 1.63 0.83 2646 18 2662 36 2653 19 2380 55 100.61 132 0 0.00 35.83 1.30 0.13201 2.74 0.18001 1.19 12.658 2.17 0.50998 1.82 0.84 2653 20 2657 40 2655 21 2506 65 100.14 158 0 0.00 33.15 1.19 0.12631 3.18 0.17973 1.25 12.735 2.32 0.51391 1.95 0.84 2650 21 2673 43 2660 22 2404 72 100.86 Marcador 1 Marcador 2 Marcador 3 Marcador 4 Marcador 5